{"id":2646,"date":"2026-04-29T16:09:12","date_gmt":"2026-04-29T08:09:12","guid":{"rendered":"https:\/\/www.bosaenergy.cn\/?p=2646"},"modified":"2026-04-29T16:09:15","modified_gmt":"2026-04-29T08:09:15","slug":"warum-stimmen-die-lade-und-entladekurven-von-lithiumbatterien-nicht-uberein-dies-liegt-am-hystereseeffekt","status":"publish","type":"post","link":"https:\/\/www.bosaenergy.cn\/de\/why-do-the-charging-and-discharging-curves-of-lithium-batteries-not-coincide-this-is-due-to-the-hysteresis-effect\/","title":{"rendered":"Warum stimmen die Lade- und Entladekurven von Lithiumbatterien nicht \u00fcberein? Dies liegt am Hystereseeffekt."},"content":{"rendered":"<h3 class=\"wp-block-heading\" id=\"ember1766\">1. Was ist Spannungshysterese?<\/h3>\n\n\n\n<p class=\"wp-block-paragraph\" id=\"ember1767\">Spannungshysterese bezeichnet das Ph\u00e4nomen, dass die Kurven f\u00fcr den Verlauf des Elektrodenpotenzials in Abh\u00e4ngigkeit von der Kapazit\u00e4t w\u00e4hrend des Lade- und Entladevorgangs nicht \u00fcbereinstimmen und somit eine Spannungshystereseschleife bilden. Spannungshysterese f\u00fchrt zu Energieverlusten und einer reduzierten Lade-\/Entladeeffizienz beim Laden und Entladen von Lithium-Ionen-Akkus.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\" id=\"ember1768\">Der Gleichgewichtspunkt der Ladekurve liegt unterhalb der Klemmenspannung, w\u00e4hrend der Gleichgewichtspunkt der Entladekurve oberhalb der Klemmenspannung liegt. Die Hauptursache f\u00fcr dieses Ph\u00e4nomen sind die Lade-, Entlade- und Stofftransportprozesse der Doppelschicht.<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter\"><img decoding=\"async\" src=\"https:\/\/media.licdn.com\/dms\/image\/v2\/D5612AQGGDyWCyZr44Q\/article-inline_image-shrink_400_744\/B56Z3YLsA6IIAY-\/0\/1777448436779?e=1779321600&amp;v=beta&amp;t=iFxmjg9yclX_VHEBLkXgHGWCq9JNQIxWdNrczcnlj5I\" alt=\"\u6587\u7ae0\u5185\u5bb9\"\/><figcaption class=\"wp-element-caption\">Hinweis: Das Laden und Entladen innerhalb des SOC-Bereichs 20%-50% f\u00fchrt zu einer sekund\u00e4ren Hystereseschleife.<\/figcaption><\/figure>\n\n\n\n<p class=\"wp-block-paragraph\" id=\"ember1770\">Ein vollst\u00e4ndiger Lade-Entlade-Zyklus (vollst\u00e4ndige Ladung und Entladung) der Batterie erzeugt die prim\u00e4re Hystereseschleife; ein unvollst\u00e4ndiger Lade-Entlade-Zyklus (Teilladung und -entladung) die sekund\u00e4re Hystereseschleife. Die beiden Kurven der prim\u00e4ren Hystereseschleife bilden die Randkurven aller Hystereseschleifen und somit die gr\u00f6\u00dfte geschlossene Schleife. Die Lade-Entlade-Kurven der sekund\u00e4ren Hystereseschleife liegen innerhalb dieser Randkurven und konvergieren gegen sie.<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter\"><img decoding=\"async\" src=\"https:\/\/media.licdn.com\/dms\/image\/v2\/D5612AQH0QjelppisoQ\/article-inline_image-shrink_1000_1488\/B56Z3YM_NHKEAQ-\/0\/1777448777955?e=1779321600&amp;v=beta&amp;t=VGie69QLRGw0S0Y2xT167C3EJxC62IfCBRizjHFgpas\" alt=\"\u6587\u7ae0\u5185\u5bb9\"\/><figcaption class=\"wp-element-caption\">Hinweis: Der Haupt-Hysteresekreis wird durch Laden und Entladen im Bereich von 0%-100% SOC ermittelt.<\/figcaption><\/figure>\n\n\n\n<h3 class=\"wp-block-heading\" id=\"ember1772\">2. Ursachen der Spannungshysterese in Lithium-Ionen-Batterien<\/h3>\n\n\n\n<p class=\"wp-block-paragraph\" id=\"ember1773\">Die Hauptursachen f\u00fcr die Spannungshysterese in Lithium-Ionen-Batterien sind der Entropieeffekt, mechanische Spannungen und mikroskopische Verzerrungen im aktiven Elektrodenmaterial w\u00e4hrend der Lithium-Insertion und -Extraktion. Lithifizierung und Delithiierung weisen unterschiedliche Gitterkonstanten auf, wodurch mechanische Spannungen in der Phasengrenze entstehen und somit ein Potenzialabfall innerhalb eines einzelnen Partikels beim \u00dcbergang vom Laden zum Entladen verursacht wird.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\" id=\"ember1774\">Auch thermodynamische Effekte sind ein Faktor, der nicht ignoriert werden kann.<\/p>\n\n\n\n<h3 class=\"wp-block-heading\" id=\"ember1775\">3. Welche Aspekte werden durch den Hystereseeffekt beeinflusst?<\/h3>\n\n\n\n<p class=\"wp-block-paragraph\" id=\"ember1776\">Gem\u00e4\u00df dem Relaxationsprinzip sollte die Spannung nach dem Laden und Entladen am jeweiligen Ladezustand (SOC) gegen den wahren Leerlaufspannungswert (OCV) konvergieren. Aufgrund der Hysterese sinkt die Spannung nach dem Entladen jedoch stets unter den wahren OCV-Wert, w\u00e4hrend sie nach dem Laden \u00fcber diesen Wert steigt. Dies f\u00fchrt zu einem erheblichen Fehler bei der Messung und Berechnung der Polarisationsspannung und beeintr\u00e4chtigt somit die Vorhersage von Batteriespannung und -leistung.<\/p>","protected":false},"excerpt":{"rendered":"<p>1. What is voltage hysteresis? Voltage hysteresis refers to the phenomenon where the electrode potential evolution curves with capacity do not coincide during the charging-discharging process, thus forming a voltage hysteresis loop. Voltage hysteresis leads to energy dissipation and reduced charging\/discharging efficiency during lithium-ion battery charging and discharging. The equilibrium point of the charging curve [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":2647,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[125],"tags":[],"class_list":["post-2646","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-blog-zh"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.5 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Why do the charging and discharging curves of lithium batteries not coincide? 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